Electrical transportation mechanisms of molybdenum disulfide flakes-graphene quantum dots heterostructure embedded in polyvinylidene fluoride polymer.

["Ooi P", "Mohammad Haniff M", "Mohd Razip Wee M", "Goh B", "Dee C", "Mohamed M", "Majlis B"]
Scientific reports 2019
Open on PubMed

In the interest of the trend towards miniaturization of electronic gadgets, this study demonstrates a high-density data storage device with a very simple three-stacking layer consisting of only one charge trapping layer. A simple solution-processed technique has been used to fabricate the tristable non-volatile memory. The three-stacking layer was constructed in between two metals to form a two-terminal metal-insulator-metal structure. The fabricated device showed a large multilevel memory hysteresis window with a measured ON/OFF current ratio of 107 that might be attributed to the high charge trapped in molybdenum disulphide (MoS2) flakes-graphene quantum dots (GQDs) heterostructure. Transmission electron microscopy was performed to examine the orientation of MoS2-GQD and mixture dispersion preparation method. The obtained electrical data was used further to speculate the possible transport mechanisms through the fabricated device by a curve fitting technique. Also, endurance cycle and retention tests were performed at room temperature to investigate the stability of the device.

5 Figures Extracted
Figure 1
Figure 1 PMC
( a ) TEM image of the MoS 2 flake decorated with GQDs. ( b ) TEM image of the GQDs on the MoS 2 . ( c ) HR-TEM image of the GQDs on the few-layer Mo...
Figure 2
Figure 2 PMC
Schematic diagram of the sandwiched MIM device. ( a ) Reference device and ( b ) tristable switching device. ( c ) SEM cross-sectional structure chara...
Figure 3
Figure 3 PMC
Absolute transmittance measurements of the tristable switching (blue dash line) and the reference (dark yellow dash line) devices in the visible regio...
Figure 4
Figure 4 PMC
I–V hysteresis window for the fabricated tristable switching device in the scanned voltage range from −1.0 to 1.5 V and vice versa. The inset shows th...
Figure 5
Figure 5 PMC
( a ) Endurance cycle and ( b ) retention tests were conducted to examine the stability performance of the fabricated tristable switching device.